Monday, 29 April 2024

Improving solar panel recyclability with lasers

Solar panels are highly recyclable, but the use of thin plastic layers to encase solar cells can cause challenges in recycling valuable materials like silicon or silver effectively.

The US Department of Energy's National Renewable Energy Laboratory (NREL) has developed a proof of concept that helps cut the use of polymers by making direct glass-to-glass welds in solar cells.

The method makes use of femtosecond lasers, a type of infrared laser that focuses energy on a very short time scale with a single laser pulse. The laser creates hermetically sealed glass-on-glass welds. Femtosecond lasers are currently used in medical eye procedures like cataract surgery today.

The laser welds would eliminate the need for plastic laminates that make recycling more difficult. At the end of their useful life span, the modules made with laser welds can be shattered, and the glass and metal wires therein can be recycled and the silicon reused.

“Most recyclers will confirm that the polymers are the main issue in terms of inhibiting the process of recycling,” said David Young, senior scientist and group manager for the High-Efficiency Crystalline Photovoltaics group in the Chemistry and Nanoscience department at NREL.






NREL published the study in the IEEE Journal of Photovoltaics. The authors said the laser is cell material agnostic, able to be used with silicon, perovskites, and cadmium telluride, among others, because the heat from the highly focused laser is confined to a few millimeters. The researchers said the welds within the glass are essentially as durable as the glass itself.

“As long as the glass doesn’t break, the weld is not going to break,” said Young. “However, not having the polymers between the sheets of glass requires welded modules to be much stiffer. Our paper showed that with proper mounting and a modification to the embossed features of the rolled glass, a welded module can be made stiff enough to pass static load testing.”

A different type of edge sealing using nanosecond lasers and a glass frit filler was tried in the past, but the welds proved too brittle for use in outdoor module designs. The femtosecond laser welds offer superior strength with hermetic sealing at a compelling cost, said NREL.

The research was conducted through the Durable Module Materials Consortium, which targets extending the useful life of solar panels to 50 years or beyond.


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Atomic Nucleus Excited with Laser: A Breakthrough after Decades

Physicists have been hoping for this moment for a long time: for many years, scientists all around the world have been searching for a very specific state of thorium atomic nuclei that promises revolutionary technological applications. It could be used, for example, to build an nuclear clock that could measure time more precisely than the best atomic clocks available today. It could also be used to answer completely new fundamental questions in physics - for example, the question of whether the constants of nature are actually constant or whether they change in space and time.

Now this hope has come true: the long-sought thorium transition has been found, its energy is now known exactly. For the first time, it has been possible to use a laser to transfer an atomic nucleus into a state of higher energy and then precisely track its return to its original state. This makes it possible to combine two areas of physics that previously had little to do with each other: classical quantum physics and nuclear physics. A crucial prerequisite for this success was the development of special thorium-containing crystals. A research team led by Prof. Thorsten Schumm from TU Wien (Vienna) has now published this success together with a team from the National Metrology Institute Braunschweig (PTB) in the journal "Physical Review Letters".
Switching quantum states

Manipulating atoms or molecules with lasers is commonplace today: if the wavelength of the laser is chosen exactly right, atoms or molecules can be switched from one state to another. In this way, the energies of atoms or molecules can be measured very precisely. Many precision measurement techniques are based on this, such as today's atomic clocks, but also chemical analysis methods. Lasers are also often used in quantum computers to store information in atoms or molecules.

For a long time, however, it seemed impossible to apply these techniques to atomic nuclei. "Atomic nuclei can also switch between different quantum states. However, it usually takes much more energy to change an atomic nucleus from one state to another – at least a thousand times the energy of electrons in an atom or a molecule," says Thorsten Schumm. "This is why normally atomic nuclei cannot be manipulated with lasers. The energy of the photons is simply not enough."

This is unfortunate, because atomic nuclei are actually the perfect quantum objects for precision measurements: They are much smaller than atoms and molecules and are therefore much less susceptible to external disturbances, such as electromagnetic fields. In principle, they would therefore allow measurements with unprecedented accuracy.
The needle in the haystack

Since the 1970s, there has been speculation that there might be a special atomic nucleus which, unlike other nuclei, could perhaps be manipulated with a laser, namely thorium-229. This nucleus has two very closely adjacent energy states – so closely adjacent that a laser should in principle be sufficient to change the state of the atomic nucleus.

For a long time, however, there was only indirect evidence of the existence of this transition. "The problem is that you have to know the energy of the transition extremely precisely in order to be able to induce the transition with a laser beam," says Thorsten Schumm. "Knowing the energy of this transition to within one electron volt is of little use, if you have to hit the right energy with a precision of one millionth of an electron volt in order to detect the transition.” It is like looking for a needle in a haystack – or trying to find a small treasure chest buried on a kilometer-long island.


The thorium crystal trick

Some research groups have tried to study thorium nuclei by holding them individually in place in electromagnetic traps. However, Thorsten Schumm and his team chose a completely different technique. "We developed crystals in which large numbers of thorium atoms are incorporated," explains Fabian Schaden, who developed the crystals in Vienna and measured them together with the PTB team. "Although this is technically quite complex, it has the advantage that we can not only study individual thorium nuclei in this way but can hit approximately ten to the power of seventeen thorium nuclei simultaneously with the laser – about a million times more than there are stars in our galaxy." The large number of thorium nuclei amplifies the effect, shortens the required measurement time and increases the probability of actually finding the energy transition.

On November 21, 2023, the team was finally successful: the correct energy of the thorium transition was hit exactly, the thorium nuclei delivered a clear signal for the first time. The laser beam had actually switched their state. After careful examination and evaluation of the data, the result has now been published.

"For us, this is a dream coming true," says Thorsten Schumm. Since 2009, Schumm had focused his research entirely on the search for the thorium transition. His group as well as competing teams from all over the world have repeatedly achieved important partial successes in recent years. "Of course we are delighted that we are now the ones who can present the crucial breakthrough: The first targeted laser excitation of an atomic nucleus," says Schumm.
The dream of the atomic nucleus clock

This marks the start of a new exciting era of research: now that the team knows how to excite the thorium state, this technology can be used for precision measurements. "From the very beginning, building an atomic clock was an important long-term goal," says Thorsten Schumm. "Similar to how a pendulum clock uses the swinging of the pendulum as a timer, the oscillation of the light that excites the thorium transition could be used as a timer for a new type of clock that would be significantly more accurate than the best atomic clocks available today."

But it is not just time that could be measured much more precisely in this way than before. For example, the Earth's gravitational field could be analyzed so precisely that it could provide indications of mineral resources or earthquakes. The measurement method could also be used to get to the bottom of fundamental mysteries of physics: Are the constants of nature really constant? Or can tiny changes perhaps be measured over time? "Our measuring method is just the beginning," says Thorsten Schumm. "We cannot yet predict what results we will achieve with it. It will certainly be very exciting."


Original publication

Laser excitation of the Th-229 nucleus, Physical Review Letters:
https://journals.aps.org/prl/accepted/2c07aYbeC981d47c171619f5604116053962ac79a, opens an external URL in a new window

Full paper (preprint): https://www.tuwien.at/fileadmin/Assets/tu-wien/News/2024/Thorium_Preprint.pdf, opens an external URL in a new window
Picture download

Download pictures provided by TU Wien and PTB

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Friday, 26 April 2024

The Quantum Mechanical Model of Atoms

From the classical models of the 18th century to the quantum revolution of the 20th century, our understanding of atomic structure has evolved. With its probabilistic nature, the quantum mechanical model has fundamentally reshaped our perception of atoms. This article explores the origins and 
fundamentals of this groundbreaking model.



Historical Development of Atomic Models

The quest to comprehend atomic structure began in earnest in the early 1800s. British scientist John Dalton proposed an early atomic theory, picturing atoms as tiny, solid, indivisible spheres. This was followed in the late 19th century by J.J. Thomson's "plum pudding" model, which depicted the atom as a diffuse cloud of positive charge with electrons embedded throughout like plums in a pudding.

However, a key experimental result in 1909 upended established conceptions of atomic structure. Physicist Ernest Rutherford directed alpha particles at a thin gold foil and detected that a small fraction rebounded backward. This suggested that the positive charge and nearly all the mass of an atom is concentrated in a tiny, dense nucleus, contrary to the plum pudding model.

Rutherford conceived the atom as a compact central nucleus orbited by electrons at a distance, akin to planets revolving around the sun. However, this raised a problem: according to classical electromagnetism, the orbiting electrons should continuously lose energy and fall into the nucleus.

Around this time, the discovery of quantized energy levels and emission spectra pointed to deficiencies in classical physics when applied at atomic scales. To address this, physicist Niels Bohr integrated the newly proposed quantum concepts into Rutherford's model. He postulated that electrons occupied discrete circular orbits at set distances from the nucleus, jumping between fixed energy levels and emitting photons when changing orbits.

While Bohr's model successfully explained patterns in atomic spectra and the stability of matter, issues remained. It relied heavily on classical notions of definite electron orbits that did not fit with emerging quantum theory. The model also could not explain finer details of atomic spectra and failed to account for electron properties like spin and magnetic moment.

As a result, the stage was set for a new model of atomic structure based firmly on the principles of quantum mechanics.
The Schrödinger Equation and Quantum Mechanical Model of Atoms

In contrast to Niels Bohr's conception of electrons as discrete particles orbiting the atomic nucleus in fixed paths, Erwin Schrödinger, inspired by de Broglie's particle-wave duality, postulated that the behavior of electrons could be mathematically described as matter waves. This model, known as the quantum mechanical model, laid the foundation for modern understanding of the atomic structure.

The quantum model describes the electrons probabilistically, using Schrodinger's wave equation to determine the likelihood of finding an electron at any given location.

Here, H represents the Hamiltonian operator, which defines the total energy of a quantum particle, and E is the particle's actual total energy. The wave function ψ at a point in space represents the electron's matter wave amplitude, though it often contains complex values.

However, the square of the magnitude of a wavefunction, |ψ|², is significant as it describes the probability of finding an electron within a specific region, serving as the probability density. Schrödinger identified these regions of space as electron orbitals, which differ from Bohr's circular orbit/planetary model.

In Schrödinger's quantum model, electrons are more accurately described as existing in "clouds" around the nucleus, organized into shells or orbitals at varying distances. The Schrödinger equation solutions (quantum numbers) provide the energetics and spatial distribution of electrons in orbitals.

Similar to Bohr's model, the energy of an electron in an atom is quantized with specific allowable values. The key distinction between Bohr's model and Schrödinger's approach is that Bohr introduced quantization arbitrarily, whereas in Schrödinger's approach, quantization naturally arises from the wave equation.

This quantum model effectively addressed inconsistencies in the classical Rutherford-Bohr theory and offered improved agreement with spectroscopic experiments. The quantum mechanical framework also provided a natural explanation for the intrinsic properties of electrons, including spin and magnetic moment, which arise from the underlying wave-particle duality.
Quantum Numbers and Atomic Orbitals

The quantum mechanical model uses four quantum numbers to define the atomic orbitals and their electron distribution.Principal Quantum Number (n): Describes an electron's energy level and average distance from the nucleus. It takes positive integer values (1, 2, 3, etc.), with higher values indicating higher energy levels.
Angular Momentum Quantum Number (l): Determines the shape of the orbital, whether it is a spherical s-orbital, dumbbell-shaped p-orbital, clover-shaped d-orbital, and so on
Magnetic Quantum Number (m₁): Indicates the spatial orientation of orbitals and varies from -l to 0 to +l based on the value of l.
Spin Quantum Number (ms): Describes an electron's spin in a magnetic field as either +1/2 (clockwise) or -1/2 (counterclockwise), with each subshell accommodating two electrons with opposite spin values.
Electron Spin and Pauli Exclusion Principle

Austrian physicist Wolfgang Pauli established a fundamental principle, the Pauli exclusion principle, which provides the final information needed to comprehend the overall behavior of electrons within atoms.

This principle is based on the electron spin quantum number, representing the electron's intrinsic spinning motion. It restricts how electrons can be configured within an atom, stating that no two electrons in the same atom can possess an identical set of all four quantum numbers. Therefore, each orbital can contain a maximum of two electrons with opposite spin quantum numbers +1/2 and -1/2.
Concluding Remarks

Despite its complexities, the quantum mechanical model excelled in explaining observations, notably in the hydrogen spectrum, where quantized orbital energies derived from quantum numbers produced multiple spectral lines. This model extended to multi-electron atoms, departing from classical particle-based views to embrace probabilities, wavefunctions, quantized energies, spin, and quantum numbers as fundamental attributes governing particles' behavior, shaping atomic and molecular structure. This transformation is a remarkable achievement in humanity's quest to understand the atom, serving as the foundation of chemistry and materials science.

Source: By Owais Ali

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Exploring the potential of single-atom catalysts

There is a high level of interest, even excitement, among chemists and materials scientists about the potential of single-atom catalysts (SACs), but their development relies on very specialized tools available only at synchrotrons like the Canadian Light Source (CLS) at the University of Saskatchewan (USask).



"This is a really exciting research area," said Dr. Peng Zhang, professor of chemistry and biomedical engineering at Dalhousie University and a long-time CLS user.

Catalysts are nanoparticles coated with materials—often expensive metals like platinum, palladium, and gold—that speed up chemical reactions. A significant drawback for conventional catalysts is that only a small percentage of the catalytic material is used in the chemical reaction, making them inefficient and wasteful, explained Zhang.

With the growing demand for clean and sustainable energy, using SACs in energy systems can help the environment and save money. SACs have benefits like making reactions more efficient, using less rare metals, and improving the performance of devices like fuel cells and batteries. They can also help store renewable energy from sources like the sun and wind, making it more reliable.

In the case of automotive catalytic converters, which are designed to convert exhaust emissions into less toxic pollutants, Zhang said less than half of the platinum atoms in the catalyst are available for the necessary chemical reaction.

The goal of SAC research is to control the surface atomic structure of catalysts with individual atoms of the catalytic material in a matrix of less expensive material, ensuring all of the material is available for the reaction. "When you design the catalyst to have a single-atom structure, you can significantly improve their activity and performance in the catalytic application," said Zhang.

The challenges of working at the level of a single atom are significant, he admitted, but that is where the CLS comes in.

"If you think about single-atom catalysts, they're so small that you need a special research tool to uncover their structure" to understand how the atoms are arranged and what atoms are present. "Even with the most powerful electron microscope, you can probably see an individual atom, but if you're using synchrotron technology, you can get a resolution 100 times smaller."

Zhang started using synchrotron facilities and techniques more than 20 years ago in his materials research as a Ph.D. student at the University of Western Ontario. When the CLS opened in 2004, "I was so excited to know that we have our first Canadian synchrotron," he said. Since then, and like his own Ph.D. supervisor, he has sent his students to the CLS and its partner synchrotron—the Advanced Photon Source (Argonne National Laboratory, near Chicago) to conduct SAC experiments on-site.

From a basic research perspective, Zhang said there remain two big hurdles in the development of single-atom catalysts.

"First, we really want to understand better why some single-atom catalysts are so good, so active, but sometimes they might not be stable after a few hours, so we have to design single-atom catalysts to be active over a long period (of time). There is a lot of work to do with these catalysts to make them more powerful and more usable."

The other challenge is ramping up SAC use to a commercial scale.

"We want to collaborate with people in the chemical industry to find real-world applications," Zhang said. "In the lab, you have very small-scale catalysis, but in the chemical industry, it is a thousand times bigger." The ability to scale up a single-atom catalytic reaction opens the door to "all kinds of chemical industry applications."

While the future potential is exciting, Zhang said fundamental SAC research would be impossible without "access to world-class facilities like the CLS and APS."

The research is published in the journal Accounts of Chemical Research.


More information: Ziyi Chen et al, Structural Analysis of Single-Atom Catalysts by X-ray Absorption Spectroscopy, Accounts of Chemical Research (2024). DOI: 10.1021/acs.accounts.3c00693

Journal information: Accounts of Chemical Research

Provided by Canadian Light Source

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Saturday, 20 April 2024

Carnot’s heat engine and the birth of thermodynamics

In late October 2021 my house’s gas-fired ‘boiler’ died suddenly. My wife and I found ourselves in a steadily cooling house wondering how to heat it. Two months later an enthusiastic start-up company installed a heat pump which, after a couple of false starts, began purring away. Being something of a nerd, I hooked up sensors to my pump to measure temperatures and energy flows. I soon came across a familiar phrase: the Carnot efficiency, a reminder of the seminal contribution that a dilettante physicist made to our understanding of thermodynamics.




Nicolas Léonard Sadi Carnot was born into a well-off and well-connected family in Paris. His father Lazare had taken part in the revolution of 1789 and gradually came to be associated with the hardline faction led by Maximilien Robespierre. Lazare reformed the army, and his successes meant he survived unscathed when Robespierre was deposed. He soon transferred his allegiance to the charismatic general Napoleon Bonaparte. But Lazare was much more than a politician – he was also a widely read polymath who wrote a book on mechanics and an analysis of the efficiency of machines. That work almost certainly had an impact on his son.
Patriot games

After finishing high school, Carnot entered the elite École Polytechnique. In 1813, as Napoleon’s regime tottered and the Allied forces pushed towards Paris, Carnot joined a regiment of fellow students, distinguishing himself in battle and being wounded. Napoleon’s regime fell all the same. Lazare was forced into exile. Carnot graduated and then moved to the military engineering school in Metz.

In 1819 a promotion brought him back to Paris where he pursued his varied interests. He was a good violinist, an excellent dancer and as a sport he enjoyed boxing. He attended lectures all over Paris, including those by the industrial chemist Nicolas Clément at the Conservatoire des Arts et Metiers – the national museum of technology.

Clément is remembered today as the person who first defined the calorie. Working with Charles Desormes, he had investigated the heat capacities of gases, and was now trying to understand steam engines. His approach combined the latest work on the behaviour of gases with the current understanding of ‘caloric’, the imponderable substance responsible for ‘heat’ changes observed during physical and chemical processes. Clément’s ideas, and the growing threat of Britain’s technological superiority, motivated Carnot to produce his own analysis.
The rest is thermodynamics

He started by asking whether there was any theoretical limit to the work obtainable from a heat engine. He implicitly rejected of the idea of caloric; heat and work were for Carnot aspects of the same thing. Following Clément he dissected the process of an engine into a cycle involving four reversible steps: two taking place at constant temperature, and two where the compression or expansion were accompanied by temperature changes. Today we refer to these as isothermal and adiabatic processes, but at a time when the very concept of energy was in its infancy, it was a new way to look at the cycle. He quantified the work done and the heat transferred at each stage using the latest data on gases to show that the heat transferred depended only on the starting and finishing points of each step, the idea of the state function. Most critically of all, he demonstrated that the temperature difference across the cycle drove the efficiency, and not the pressure inside the engine. In other words, work was only possible when heat passed from hot to cold, which he felt was a new law of nature. In consequence, he concluded that the nature of the working fluid – steam or air – was immaterial.




The small book, that Carnot had privately printed in 600 copies, fell flat. There is a sense that its originality went unrecognised at a time when the practical, material problems of engines loomed much larger than the theory. By the time Carnot fell ill in 1832 with scarlet fever and died of cholera, he had been forgotten. But his death led to a re-evaluation of his essay. The French physicist Émile Clapeyron wrote first an obituary and then a more detailed analytical development of Carnot’s idea. During a visit to Paris, William Thomson (later Lord Kelvin) was unable to find Carnot’s book but read Clapeyron’s paper. By 1850, he and Rudolf Clausius separately reconciled Carnot’s ideas about motive power with James Joule’s measurements of the equivalence of heat and work, using the concepts of absolute temperature and entropy. Thermodynamics was born.

Carnot’s insight is all around us and his ideas have become ever more critical to our decision-making in a warming world. As I listen to my purring pump, I wonder whether Carnot actually imagined that one might turn his theoretical machine on its head and use an external motive force – electricity – to generate heat, and keep a family warm on a cold night.

source: Andrea Sella

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Study uses thermodynamics to describe expansion of the universe

The idea that the universe is expanding dates from almost a century ago. It was first put forward by Belgian cosmologist Georges Lemaître (1894–1966) in 1927 and confirmed observationally by American astronomer Edwin Hubble (1889-1953) two years later. Hubble observed that the redshift in the electromagnetic spectrum of the light received from celestial objects was directly proportional to their distance from Earth, which meant that bodies farther away from Earth were moving away faster and the universe must be expanding.

A surprising new ingredient was added to the model in 1998 when observations of very distant supernovae by the Supernova Cosmology Project and the High-Z Supernova Search Team showed that the universe is accelerating as it expands, rather than being slowed down by gravitational forces, as had been supposed. This discovery led to the concept of dark energy, which is thought to account for more than 68% of all the energy in the currently observable universe, while dark matter and ordinary matter account for about 27% and 5% respectively.



"Measurements of redshift suggest that the accelerating expansion is adiabatic [without heat transfer] and anisotropic [varying in magnitude when measured in different directions]," said Mariano de Souza, a professor in the Department of Physics at São Paulo State University (UNESP) in Rio Claro, Brazil. "Fundamental concepts in thermodynamics allow us to infer that adiabatic expansion is always accompanied by cooling due to the barocaloric effect [pressure-induced thermal change], which is quantified by the Grüneisen ratio [Γ, gamma]."

In 1908, German physicist Eduard August Grüneisen (1877–1949) proposed a mathematical expression for Γeff, the effective Grüneisen parameter, an important quantity in geophysics that often occurs in equations describing the thermoelastic behavior of material. It combines three physical properties: expansion coefficient, specific heat, and isothermal compressibility.

Almost a century later, in 2003, Lijun Zhu and collaborators demonstrated that a specific part of the Grüneisen parameter called the Grüneisen ratio, defined as the ratio of thermal expansion to specific heat, increases significantly in the vicinity of a quantum critical point owing to the accumulation of entropy. In 2010, Souza and two German collaborators showed that the same thing happens near a finite-temperature critical point.

Now Souza and fellow researchers at UNESP have used the Grüneisen parameter to describe intricate aspects of the expansion of the universe in an article published in the journal Results in Physics, presenting part of the Ph.D. research of first author Lucas Squillante, currently a postdoctoral fellow under Souza's supervision.

"The dynamics associated with the expansion of the universe are generally modeled as a perfect fluid whose equation of state is ω = p/ρ, where ω [omega] is the equation of state parameter, p is pressure, and ρ [rho] is energy density. Although ω is widely used, its physical meaning hadn't yet been appropriately discussed. It was treated as merely a constant for each era of the universe. One of the important results of our research is the identification of ω with the effective Grüneisen parameter by means of the Mie-Grüneisen equation of state," Souza said.

The Mie–Grüneisen equation of state relates to pressure, volume and temperature, and is often used to determine the pressure in a shock-compressed solid.

The authors show, using the Grüneisen parameter, that continuous cooling of the universe is associated with a barocaloric effect that relates pressure and temperature and occurs owing to adiabatic expansion of the universe. On this basis, they propose that the Grüneisen parameter is time-dependent in the dark energy-dominated era (the current universe era).

One of the interesting aspects of this research is its use of thermodynamics and solid-state physics concepts such as stress and strain to describe the anisotropic expansion of the universe. "We show that the Grüneisen parameter is naturally embodied in the energy–momentum stress tensor in Einstein's famous field equations, opening up a novel way to investigate anisotropic effects associated with the expansion of the universe. These don't rule out the possibility of a Big Rip," Souza said.

The Big Rip hypothesis, first put forward in 2003 in an article published in Physical Review Letters, posits that if the quantity of dark energy is sufficient to accelerate the expansion of the universe beyond a critical velocity, this could tear the "fabric" of space-time and rip apart the universe.

"Also in the perspective of the Grüneisen parameter, we conjecture that the shift from a decelerating expansion regime [in the radiation and matter-dominated eras] to an accelerating expansion regime [in the dark energy-dominated era] resembles a thermodynamic phase transition. This is because Γeff changes sign when the expansion changes from decelerating to accelerating. The sign change resembles the typical signature of phase transitions in condensed matter physics," Souza said.

Dark energy is often associated with the cosmological constant Λ [lambda], originally introduced by Einstein in 1917 as a repulsive force required to keep the universe in static equilibrium. Einstein later rejected the concept, according to some accounts. It was rehabilitated when the expansion of the universe was found to be accelerating instead of decelerating. The hegemonic model, known as Λ-CMD (Lambda-Cold Dark Matter), gives the cosmological constant a fixed value. That is, it assumes that the density of dark energy remains constant as the universe expands. However, other models assume that the density of dark energy, and hence Λ, vary over time.

"Assigning a fixed value to lambda means also assigning a fixed value to omega, but recognition of ω as the effective Grüneisen parameter enables us to infer time dependency for ω as the universe expands in the dark energy-dominated era. This directly entails time dependency for Λ, or the universal gravitation constant," Souza said.

The study could lead to important developments insofar as it affords a glimpse of a novel interpretation of the expansion of the universe in terms of thermodynamics and condensed matter physics.

Besides Souza and Squillante, the other co-authors of the article are Antonio Seridonio (UNESP Ilha Solteira), Roberto Lagos-Monaco (UNESP Rio Claro), Gabriel Gomes (Institute of Astronomy, Geophysics and Atmospheric Sciences, University of São Paulo, IAG-USP), Guilherme Nogueira (UNESP Rio Claro), and Ph.D. candidate Isys Mello, supervised by Souza.

SOURCE: José Tadeu Arantes, FAPESP

More information: Lucas Squillante et al, Exploring the expansion of the universe using the Grüneisen parameter, Results in Physics (2024). DOI: 10.1016/j.rinp.2024.107344

Journal information: Physical Review Letters

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Thursday, 18 April 2024

Internet can achieve quantum speed with light saved as sound




Researchers at the University of Copenhagen's Niels Bohr Institute have developed a new way to create quantum memory: A small drum can store data sent with light in its sonic vibrations, and then forward the data with new light sources when needed again. The results demonstrate that mechanical memory for quantum data could be the strategy that paves the way for an ultra-secure internet with incredible speeds.

The research is published in the journal Physical Review Letters.

Just beneath Niels Bohr's old office is a basement where scattered tables are covered with small mirrors, lasers and an agglomeration of all types of devices connected by webs of wires and heaps of tape. It looks like a child's project gone too far, one that their parents have tried in vain to get them to clean up.

While it is difficult for the untrained eye to discern that these tables are actually the home to an array of world-leading research projects, the important stuff is happening within worlds so small that not even Newton's laws apply. This is where Niels Bohr's quantum physical heirs are developing the most cutting-edge of quantum technologies.

One of these projects stands out—for physicists at least—by the fact that a gizmo visible to the naked eye is able to achieve quantum states. The quantum drum is a small membrane made of a ceramic, glass-like material with holes scattered in a neat pattern along its edges.

When the drum is beaten with the light of a laser, it begins vibrating, and does this so quickly and without interference that quantum mechanics come into play. This property has long since caused a stir by opening up a number of quantum technological possibilities.

Now, a collaboration across various quantum areas at the Institute has demonstrated that the drum can also play a key role for the future's network of quantum computers. Like modern alchemists, researchers have created a new form of "quantum memory" by converting light signals into sonic vibrations.

In their just-published research article, the researchers have proven that quantum data from a quantum computer emitted as light signals—e.g., through the type of fiber-optic cable already used for high-speed internet connections—can be stored as vibrations in the drum and then forwarded.


Previous experiments had demonstrated to researchers that the membrane can remain in an otherwise fragile quantum state. On this basis, they believe that the drum should be able to receive and transmit quantum data without it "decohering," i.e., losing its quantum state when the quantum computers are ready.

"This opens up great perspectives for the day when quantum computers can really do what we expect them to. Quantum memory is likely to be fundamental for sending quantum information over distances. So, what we've developed is a crucial piece in the very foundation for an internet of the future with quantum speed and quantum security," says postdoc Mads Bjerregaard Kristensen of the Niels Bohr Institute, lead author of the new research article.
Ultra-fast, ultra-secure

When transferring information between two quantum computers over a distance—or among many in a quantum internet—the signal will quickly be drowned out by noise. The amount of noise in a fiber-optic cable increases exponentially the longer the cable is. Eventually, data can no longer be decoded.

The classical Internet and other major computer networks solve this noise problem by amplifying signals in small stations along transmission routes. But for quantum computers to apply an analogous method, they must first translate the data into ordinary binary number systems, such as those used by an ordinary computer.

This won't do. Doing so would slow the network and make it vulnerable to cyberattacks, as the odds of classical data protection being effective in a quantum computer future are very bad.

"Instead, we hope that the quantum drum will be able to assume this task. It has shown great promise as it is incredibly well-suited for receiving and resending signals from a quantum computer. So, the goal is to extend the connection between quantum computers through stations where quantum drums receive and retransmit signals, and in so doing, avoid noise while keeping data in a quantum state," says Kristensen.

"In doing so, the speeds and advantages of quantum computers, e.g., in relation to certain complex calculations, will extend across networks and the Internet, as they will be achieved by exploiting properties like superposition and entanglement that are unique to quantum states."



If successful, the stations will also be able to extend quantum-secured connections, whose quantum codes could also be lengthened by the drum. These secure signals could be sent over various distances—whether around a quantum network or across the Atlantic—in the quantum internet of the future.

Flexible, practical and possibly groundbreaking as quantum RAM

Research is being conducted elsewhere to an alternative where a data-carrying light source is directed at an atomic system and temporarily shifts the electrons in the atom, but the method has its limitations.

"There are limits to what you can do with an atomic system, as we can't design atoms or the frequency of the light that they can interact with ourselves. Our relatively 'large' mechanical system provides more flexibility. We can tinker and adjust, so that if new discoveries change the rules of the game, there is a good chance that the quantum drum can be adapted," explains Professor Albert Schliesser, co-author of the research article.

"For better or worse, our abilities as researchers are mostly what define the limits for how well it all works," he points out.

The drum is the latest and most serious take on mechanical quantum memory as it combines a number of properties: The drum has low signal loss—i.e., the data signal's strength is well retained. It also has the tremendous advantage of being able to handle all light frequencies, including the frequency used in the fiber optic light cables upon which the modern Internet is built.

The quantum drum is also convenient because data can be stored and read whenever needed. And the record-long 23 milliseconds of memory time already achieved by researchers makes it far more likely that the technology may one day become a building block for systems of quantum networks as well as the hardware in quantum computers.

"We are out early with this research. Quantum computing and communication are still at an early stage of development, but with the memory we've obtained, one can speculate that the quantum drum will one day be used as a kind of quantum RAM, a kind of temporary working memory for quantum information. And that would be groundbreaking," says the professor.

More information: Mads Bjerregaard Kristensen et al, Long-lived and Efficient Optomechanical Memory for Light, Physical Review Letters (2024). DOI: 10.1103/PhysRevLett.132.100802

Journal information: Physical Review Letters

Provided by University of Copenhagen

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ModelAngelo software expands cryo-EM toolkit with faster atomic model building and identification of novel proteins

New cryo-EM imaging software incorporates cutting-edge algorithms and neural networks to remedy a long-standing problem in structural biology and enables the identification of unknown components



Electron cryo-microscopy (cryo-EM) is a crucial tool for determining biological structures, which in turn, allow researchers to advance understanding of the molecular processes which underpin life. Once experimental images are captured, software such as RELION can be used to reconstruct density maps of the imaged biomolecules to create three-dimensional volumes. However, to achieve an atomic structure, experienced researchers must spend a considerable amount of time manually interpreting the densities in three-dimensional computer graphics programmes. To overcome this, Kiarash Jamali, a Ph.D. student in Sjors Scheres’ group in the LMB’s Structural Studies Division, has developed the programme ModelAngelo, which is not only capable of automated model building at atomic levels, but has also shown aptitude at identifying novel proteins.

The neural networks behind ModelAngelo are based on the same fundamental building blocks as those used by ChatGPT and AlphaFold. However, these previous machine learning approaches were able to utilise anywhere between hundreds of thousands to tens of millions of pieces of training data. In contrast, there are fewer than 13,000 cryo-EM structures which have been solved to resolutions greater than 4Å. To overcome this limitation, ModelAngelo was designed to use a multi-modal, machine-learning approach, which incorporates three different data inputs, each in different forms; three-dimensional volume cryo-EM maps, text indicating the amino acid sequences of the proteins in the sample, and graphs of the intermediate atomic model built at each step.

Using these specialist neural networks, ModelAngelo is able to produce models of a comparable quality to expert structuralists manually interpreting results in a fraction of the time. The programme has also demonstrated success in modelling nucleotide backbones.

To illustrate the advances presented by ModelAngelo, it needed just a few hours to build complex subunit proteins that perform photosynthesis in algae to a high degree of completion (the supercomplex of the phycobilisome and transmembrane light-harvesting complexes). This large complex containing over 150,000 residues in 81 unique protein chains previously took months of work for researchers to manually build the atomic model.

Beyond the benefit of saving huge amounts of time in structural studies, ModelAngelo has shown further use with its capabilities to identify novel proteins which were previously unknown to researchers using the cryo-EM map alone. To achieve this, Lukas Käll at the KTH Royal Institute of Technology in Stockholm, Sweden, further developed the software, implementing a database searching algorithm using hidden Markov Models. Again studying the above supercomplex, ModelAngelo was able to identify six novel protein chains that prior to this were unknown, despite extensive manual effort when mapping the structure.

ModelAngelo is a transformative addition to the toolkit of structural biology. It promises to drastically reduce the time needed for atomic structure determination, and has proved itself more capable than humans in identifying proteins with unknown sequences. Already, it is in use in several different projects, including in drug discovery pipelines in pharmaceutical companies. Aside from its applicable uses, the use of such divergent data sources represents a significant advancement in the field of machine learning, and has the potential to be further developed and implemented in a vast range of scenarios.

For his work designing and implementing ModelAngelo, Kiarash received the 2023 Perutz Student Prize.

This work was funded by UKRI MRC, EU Horizon 2020, the National Institutes of Health and the Knut and Alice Wallenberg Foundation.

Further references

Automated model building and protein identification in cryo-EM maps. Jamali, K., Käll, L., Zhang, R., Brown, A., Kimanius, D., and Scheres, SHW. Nature
Sjors’ group page
Lukas Käll’s page

Previous Insight on Research articles
Atomic advance for cryo-EM

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Tuesday, 16 April 2024

A Soap Bubble Becomes a Laser

Soap bubbles are known for their attention-grabbing effect on toddlers, and now researchers have shown that these objects have another dazzling use—generating color-tunable laser light [1]. They demonstrated that a dye dissolved in the soap solution of such a bubble can amplify light circulating in the spherical shell and produce laser light. This light is visible as a glowing ring around the bubble. Such “bubble lasers” could act as precision sensors for measuring atmospheric pressure or for detecting changes in an electric field.

The allure of bubbles comes in large part from their interaction with light. As soap bubbles dance through the air, they sparkle like glitter, shifting hues as they move. This phenomenon, known as iridescence, comes from the interference of light waves within a bubble’s soapy shell.

Researchers have also shown that laser light can propagate within a bubble’s shell, branching out into filamentous structures that resemble lightning [2]. The light in each of the thousands of glowing filaments that can develop stays focused. These observations led Matjaž Humar and Zala Korenjak of the Jožef Stefan Institute and the University of Ljubljana, both in Slovenia, to ask if a bubble could be used to create laser light. Other kinds of spherical shells have been used as laser cavities, Humar says, so “I wondered if the bubble might work in that way.”



To test the idea, Humar and Korenjak created a device using a standard soap bubble solution mixed with a fluorescent dye. The bubble was held on the end of a capillary tube and illuminated with a pulsed laser. The researchers then monitored the spectrum of the light emitted from the bubble as they increased the pulsed laser’s intensity.

At low intensities, the duo observed only fluorescence, light that appeared as emission over a broad range of wavelengths. Increasing the intensity of the pulsed laser, Humar and Korenjak observed a ring of bright light on the bubble. Beyond a threshold intensity, they also detected sharp peaks in the bubble’s emission spectrum, which they linked to the onset of lasing.

Lasers have three main components: an energy source, an optical resonator, and a so-called gain medium—a material that amplifies the light in the resonator. Humar says that the pulsed laser acted as the energy source, the bubble’s shell as the resonator, and the dye as the gain medium. When the path of the fluorescence circulating within the bubble’s shell was the right length to allow the light-wave peaks of specific wavelengths to overlap on consecutive loops, the light at these wavelengths intensified, which led to lasing.

Humar notes that while these experiments showed that the idea works, soap bubble lasers aren’t practical. “Water constantly evaporates from the bubbles, changing their shape and size and the spectrum of light that they emit,” he says. For a more stable laser, he and Korenjak turned to smectic liquid-crystal bubbles, which Humar says can, in principle, “survive indefinitely without any changes.”

The researchers showed that they could tune the wavelength of the light emitted from a smectic-bubble laser by adding air to the bubble or by altering external parameters such as an electric field or the surrounding atmospheric pressure. All of these factors affected the radius of the bubble, which determined the wavelength of emitted laser light. Proof-of-principle measurements indicated that electric fields as small as 0.35 V/mm and pressure changes of 0.024 pascals could be detected, on par or better than some existing sensors. For pressure changes, the bubbles have an especially wide range of sensitivity.

“The size of the bubbles, and therefore their emission spectrum, can be dynamically changed by inflating and deflating the bubble, offering unprecedented tunability,” says liquid-crystal researcher Teresa Lopez-Leon of ESPCI ParisTech. Lopez-Leon notes that lasing has previously been achieved using droplets of smectic liquid crystals but not bubbles, whose very thin shells give them unique mechanical and optical properties. Lopez-Leon also calls attention to the ease with which Humar and Korenjak can create their smectic bubble lasers. “They are fascinating objects,” she says.


–Katherine Wright

Katherine Wright is the Deputy Editor of Physics Magazine.
ReferencesZ. Korenjak and M. Humar, “Smectic and soap bubble optofluidic lasers,” Phys. Rev. X 14, 011002 (2024).
A. Patsyk et al., “Observation of branched flow of light,” Nature 583, 60 (2020).


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Monday, 15 April 2024

HoloGW Project: Tackling Unresolved Mysteries in Astrophysics and Cosmology

The European Research Council (ERC) has awarded an Advanced Grant to David Mateos, an ICREA researcher in the Department of Quantum Physics and Astrophysics and member of the UB Institute of Cosmos Sciences (ICCUB), to use holography in the field of gravitational waves. The HoloGW project has been granted funding of 2.5 million euros to tackle unresolved issues in cosmology and astrophysics from a new perspective.



Gravitational waves are slight disturbances in space-time, as postulated by Einstein's theory of general relativity.

The first detection in 2015 was a real experimental revolution. Almost everything we knew at the time about the universe was based on the light coming to us from all directions.

David Mateos, ICREA Researcher, Department of Quantum Physics and Astrophysics, University of Barcelona

The UB researcher emphasizes the significance of the discovery: “Listening to the universe through gravitational waves is as ground-breaking a change as adding sound to silent films.”

The goal of the ERC-funded project HoloGW is to capitalize on this experimental breakthrough and obtain a profound knowledge of “the properties of quantum matter that generate gravitational waves” through the application of holography, a technology derived from string theory.

Mateos added, “This matter is often found in extreme conditions, such as in the early universe, in neutron star or black hole mergers, near a space-time singularity, and so on. This makes it very difficult to study with conventional methods.”

Mateos is optimistic that holography will help resolve fundamental challenges in astrophysics and cosmology that have been unresolved for many years.
Advanced Grants, a Fundamental Tool to Promote Research

The European Research Council (ERC) has awarded 255 Advanced Grants, totaling an investment of 652 million euros, to support cutting-edge research across various disciplines such as humanities, social sciences, physics, and medicine. This grant is considered the most prestigious and competitive offered by the Council, as it enables researchers to pursue projects that could lead to major scientific breakthroughs.

Source: https://web.ub.edu/en

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Saturday, 13 April 2024

Near perfect' control of single atoms is major advance toward quantum computing


A new fabrication process that could be used to build a quantum computer achieves an almost zero failure rate and has the potential to be scaled up, according to new research from engineers and physicists at UCL.

The study, published in Advanced Materials, describes the first successful attempt to reliably position single atoms in an array since the idea was first proposed 25 years ago. The near 100% precision and scalability of the approach raises the possibility of building a quantum computer capable of tackling the world's most complex problems—though substantial engineering challenges still need to be overcome to realize that ambition.

Theoretically, quantum computing has the potential to solve complex problems that "classical" binary, transistor-based computers will never be able to tackle. One way the gates in a universal quantum computer, known as qubits (quantum bits), can be created is from single atoms placed in silicon, cooled to extremely low temperatures to keep their quantum properties stable. They can then be manipulated with electrical and magnetic signals to process information, in much the same way that a binary transistor in a classical computer is manipulated to output a zero or a one.


This allows the computer to harness the power of quantum mechanics, the deep laws of physics that determine how the universe works. This includes phenomena such as superposition, or the ability of qubits to be in many different arrangements at the same time, and quantum entanglement, which is the ability of qubits to be inextricably linked.

These features mean complex problems can be represented in new ways. For a problem with an exceptionally large number of possible outcomes, a quantum computer is able to consider the possibilities simultaneously, rather than one at a time like a normal computer would—which would take today's best supercomputer millions of years to process.

Various approaches to building a quantum computer are underway, but none have yet managed to reach the scale and low error rates required.

One approach to building a quantum computer is to precisely position individual "impurity" atoms in a silicon crystal, which allows manipulation of their quantum properties to form qubits. One of the benefits of this approach is that it has inherently low qubit error rates and is underpinned by scalable silicon microelectronics technologies.

The standard approach uses phosphorus as the impurity atom, but because single phosphorus atoms can only be positioned with a 70% success rate, this system remains some way off from the near-zero failure rate that is required to build a quantum computer.

In this study, researchers at UCL hypothesized that arsenic might be a better material than phosphorus to achieve the low failure rate needed to build a quantum computer.


They used a microscope capable of identifying and manipulating single atoms, similar to the needle on a vinyl record player, to precisely insert arsenic atoms into a silicon crystal. They then repeated this process to build a 2x2 array of single arsenic atoms, ready to become qubits.


Dr. Taylor Stock, first author of the study from UCL Electronic & Electrical Engineering, said, "The most advanced quantum computing systems in development are still grappling with the twin problems of how to mitigate qubit error rates and how to scale up the number of qubits.

"Reliable, atomically-precise fabrication could be used to build a scalable quantum computer in silicon. The prevailing view was that single-atom fabrication using arsenic would suffer the same problems as phosphorus. But based on our calculations, we realized that single arsenic atoms might be placed more reliably than phosphorus, and we've been able to do this successfully.

"We've been conservative in estimating that we can place atoms with 97% accuracy, but we are confident that this can be increased to 100% in the near future."

At the moment, the method developed in the study requires each atom to be positioned by hand one at a time, which takes several minutes. Theoretically this process can be repeated indefinitely, but in practical terms it will be necessary to automate and industrialize the process in order to build a universal quantum computer—which means creating arrays of millions, tens of millions or even billions of qubits.

The authors say that the silicon semiconductor industry, currently worth around $550 billion, should be able to contribute to advancing the field, as arsenic and silicon are both commonly used in the construction of semiconductors for classical computing. The approach developed in this study is expected to be highly compatible with current semiconductor processing and could hopefully be integrated once engineering challenges have been addressed.

Professor Neil Curson, senior author of the study from UCL Electronic & Electrical Engineering, said, "The ability to place atoms in silicon with near perfect precision and in a way that we can scale up is a huge milestone for the field of quantum computing, the first time that we've demonstrated a way of achieving the accuracy and scale required.

"We now have a huge engineering challenge ahead to be able to do this more quickly and easily—but this is the first time that I've felt certain that a universal quantum computer can be built."

Source: Taylor J. Z. Stock et al, Single‐Atom Control of Arsenic Incorporation in Silicon for High‐Yield Artificial Lattice Fabrication, Advanced Materials (2024). DOI: 10.1002/adma.202312282

Journal information: Advanced Materials

Provided by University College London

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